'Reinvented' molten sodium battery operates at lower temperatures

July 22, 2021 // By Rich Pell
'Reinvented' molten sodium battery operates at lower temperatures
Researchers at Sandia National Laboratories say they have designed a new class of molten sodium batteries for grid-scale energy storage.

While molten sodium batteries have been used for many years to store energy from renewable sources, commercially available molten sodium batteries - called sodium-sulfur batteries - typically operate at 520-660 degrees Fahrenheit. Sandia's new molten sodium-iodide battery, however, say the researchers, operates at a much cooler 230 degrees Fahrenheit instead.

“We’ve been working to bring the operating temperature of molten sodium batteries down as low as physically possible,” says Leo Small, the lead researcher on the project. “There’s a whole cascading cost savings that comes along with lowering the battery temperature. You can use less expensive materials. The batteries need less insulation and the wiring that connects all the batteries can be a lot thinner.”

However, say the researchers, the battery chemistry that works at 550 degrees doesn’t work at 230 degrees. Among the major innovations that allowed the lower operating temperature of the new battery was the development of what the researchers call a "catholyte" - a liquid mixture of two salts, in this case, sodium iodide and gallium chloride.

A basic lead-acid battery - such as is commonly used as a car ignition battery - has a lead plate and a lead dioxide plate with a sulfuric acid electrolyte in the middle. As energy is discharged from the battery, the lead plate reacts with sulfuric acid to form lead sulfate and electrons, which in turn start the car and return to the other side of the battery, where the lead dioxide plate uses the electrons and sulfuric acid to form lead sulfate and water.

For the new molten sodium battery, the lead plate is replaced by liquid sodium metal, and the lead dioxide plate is replaced by a liquid mixture of sodium iodide and a small amount of gallium chloride. When energy is discharged from the new battery, the sodium metal produces sodium ions and electrons.

On the other side, the electrons turn iodine into iodide ions. The


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